A CO-derived iron dicarbyne that releases olefin upon hydrogenation.

نویسندگان

  • Daniel L M Suess
  • Jonas C Peters
چکیده

An iron diphosphineborane platform that was previously reported to facilitate a high degree of N2 functionalization is herein shown to effect reductive CO coupling. Disilylation of an iron dicarbonyl precursor furnishes a structurally unprecedented iron dicarbyne complex. Several complexes related to this process are also characterized which allows for a comparative analysis of their respective Fe-B and Fe-C bonding. Facile hydrogenation of the iron dicarbyne at ambient temperature and 1 atm H2 results in release of a CO-derived olefin.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 135 34  شماره 

صفحات  -

تاریخ انتشار 2013